113361-69-6

Basic information

• Product Name: ethyl 3-[2'-(3-ethoxy-3-oxo-1-propenyl)[1,1'-biphenyl]-2-yl]acrylate
• Synonyms: ethyl 3-[2'-(3-ethoxy-3-oxo-1-propenyl)[1,1'-biphenyl]-2-yl]acrylate
• CAS NO: 113361-69-6
• Molecular Formula: C22H22O4
• Molecular Weight: 350.40768
• Mol File: 113361-69-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ethyl 3-[2'-(3-ethoxy-3-oxo-1-propenyl)[1,1'-biphenyl]-2-yl]acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-[2'-(3-ethoxy-3-oxo-1-propenyl)[1,1'-biphenyl]-2-yl]acrylate(113361-69-6)
• EPA Substance Registry System: ethyl 3-[2'-(3-ethoxy-3-oxo-1-propenyl)[1,1'-biphenyl]-2-yl]acrylate(113361-69-6)

Safety Data

• Hazardous Substances Data: 113361-69-6(Hazardous Substances Data)

Upstream product

• 1210-05-5 Biphenyl-2,2'-dicarbaldehyde 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 26260-02-6 2-iodobenzaldehyde 
• 6630-33-7 ortho-bromobenzaldehyde 

Relevant articles and documents

A modified Cu(0)-Cu(I)-mediated Caryl-CarylUllmann coupling for the synthesis of biaryls

A novel Cu(0)-Cu(I)-mediated Caryl-CarylUllmann coupling has been successfully developed. The use of Cu(I) salts allowed the reactions to proceed under relatively mild conditions (65?°C in DMSO for 15–72?h). The developed method was compatible with a relatively wide range of functional groups simultaneously present on the aromatic ring of different electronic nature. The aryl halides with an electron-withdrawing group ortho to the halide or an electron-donating group meta or para to the halide furnished the corresponding products in good to excellent yields (up to 98%).