113388-13-9Relevant academic research and scientific papers
Palladium-mediated cyclization of 1,5-hexadien-3-ols to 1-methyl-1,3-cyclopentadienes
Zair,Santelli-Rouvier,Santelli
, p. 3313 - 3324 (1993)
Treatment of 1,5-hexadien-3-ols in acetic acid by Pd(o) [Pd(PPh3)4] led to 1-methyl-1,3-cyclopentadienes. Cyclization is improved by the presence of catalytic amount of trifluoroacetic acid. Mechanism is discussed from the observed r
Palladium-Mediated Cyclization of 1,5-Hexadien-3-ols to 1-Methyl-1,3-cyclopentadienes
Zair, Touriya,Santelli-Rouvier, Christiane,Santelli, Maurice
, p. 4501 - 4502 (2007/10/02)
Treatment of 1-allyl-2-alkenylidenecyclohexanols in acetic acid by the Pd(0) complex led to 8-methyl bicyclonona-1(6),7-dienes.In contrast, only few examples of cyclization vs elimination were observed in acyclic 1,5-hexadien-3-ols.Keyw
