1133982-03-2Relevant academic research and scientific papers
Protecting group and solvent control of stereo-and chemoselectivity in glucal 3-carbamate amidoglycosylation
Gupta, Ritu,Sogi, Kimberly M.,Bernard, Sarah E.,Decatur, John D.,Rojas, Christian M.
supporting information; experimental part, p. 1527 - 1530 (2009/09/06)
In the Rh2(OAc)4-catalyzed amidoglycosylation of glucal 3-carbamates, anomeric stereoselectivity and the extent of competing C3-H oxidation depend on the 4O and 6O protecting groups. Acyclic protection permits high α-anomer selectivi
