1134474-75-1Relevant academic research and scientific papers
Synthesis of gabosine A and N from ribose by the use of ring-closing metathesis
Monrad, Rune Nygaard,Fanefjord, Mette,Hansen, Flemming Gundorph,Jensen, N. Michael E.,Madsen, Robert
experimental part, p. 396 - 402 (2009/07/25)
A concise synthetic route is described for the synthesis of gabosine A and N. The key step uses a zinc-mediated tandem reaction where methyl 5-deoxy-5-iodo-2,3-O-isopropylidene-β-D-ribofuranoside is fragmented to give an unsaturated aldehyde which is ally
