113451-09-5Relevant academic research and scientific papers
Ortho-Selective Side-Chain Nitration of Methyl-Substituted Alkenoylbenzenes and Its Application to Synthesis of 4-Nitro-1-tetralones
Keumi, Takashi,Inagaki, Toshihiko,Nakayama, Norihiro,Taniguchi, Masaaki,Morita, Toshio,Kitajima, Hidehiko
, p. 4034 - 4038 (2007/10/02)
Methyl-substituted alkenoylbenzenes 1a-m involving acryoyl, methacryloyl, β-(ethoxycarbonyl)acryloyl, crotonoyl, and cinnamoyl groups as alkenoyl functions reacted with fuming nitric acid in acetic anhydride to give 2-(nitromethyl)alkenoylbenzenes 2a-m in
Convenient Synthesis of 4-Nitrotetralones by Selective Side-chain Nitration of Methyl-substituted Acryloylbenzenes, followed by Intramolecular Michael Reaction
Keumi, Takashi,Inagaki, Toshihiko,Nakayama, Norihiro,Morita, Toshio,Kitajima, Hidehiko
, p. 1091 - 1092 (2007/10/02)
Reaction of polymethyl-substituted acryloylbenzenes (1) with fuming nitric acid in acetic anhydride gave the products (2) derived from selective side-chain nitration at the ortho-position; the subsequent intramolecular michael reaction leads to exclusive
