113466-88-9

Basic information

• Product Name: Cyclopenta[b]pyrrol-2(1H)-one, 3,3a,4,6a-tetrahydro-, cis- (9CI)
• Synonyms: Cyclopenta[b]pyrrol-2(1H)-one, 3,3a,4,6a-tetrahydro-, cis- (9CI);cis-3,3a,4,6a-tetrahydro-Cyclopenta[b]pyrrol-2(1H)-one (Relative struc)
• CAS NO: 113466-88-9
• Molecular Formula: C7H9NO
• Molecular Weight: 123.15246
• Product Categories: PYRROLIDINE
• Mol File: 113466-88-9.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopenta[b]pyrrol-2(1H)-one, 3,3a,4,6a-tetrahydro-, cis- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopenta[b]pyrrol-2(1H)-one, 3,3a,4,6a-tetrahydro-, cis- (9CI)(113466-88-9)
• EPA Substance Registry System: Cyclopenta[b]pyrrol-2(1H)-one, 3,3a,4,6a-tetrahydro-, cis- (9CI)(113466-88-9)

Safety Data

• Hazardous Substances Data: 113466-88-9(Hazardous Substances Data)

Upstream product

• 147528-95-8 C₁₃H₂₇NOSi₂ 
• 72845-09-1 2-(cyclopent-2-en-1-yl)acetamide 
• 933-03-9 2-(cyclopent-2-en-1-yl)acetyl chloride 
• 13668-61-6 (cyclopent-2-eneyl)acetic acid 
• 100556-58-9 8-exo-iodo-2-azabicyclo<3.3.0>octan-3-one 
• 108-24-7 acetic anhydride 

Downstream Products

• 91448-19-0 2-azabicyclo<3.3.0>octan-3-one 

Relevant articles and documents

Synthesis of Secondary Unsaturated Lactams via an Aza-Heck Reaction

The preparation of unsaturated secondary lactams via the palladium-catalyzed cyclization of O-phenyl hydroxamates onto a pendent alkene is reported. This method provides rapid access to a broad range of lactams that are widely useful building blocks in alkaloid synthesis. Mechanistic studies support an aza-Heck-type pathway.

STEREOCONTROLLED SYNTHESIS OF DIAMINES FROM IODOLACTAMS

Displacement of iodide from iodolactams by azide occurs with retention of configuration if a catalytic amount of NaH is added, due to the intervention of an N-acyl-aziridine.Several diamine equivalents and a spermidine analogue are prepared in this way.