113477-58-0

Basic information

• Product Name: Quinoxaline, 1,2,3,4-tetrahydro-2,3-bis(1-methyl-2-propenyl)-
• CAS NO: 113477-58-0
• Molecular Formula: C16H22N2
• Mol File: 113477-58-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Quinoxaline, 1,2,3,4-tetrahydro-2,3-bis(1-methyl-2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoxaline, 1,2,3,4-tetrahydro-2,3-bis(1-methyl-2-propenyl)-(113477-58-0)
• EPA Substance Registry System: Quinoxaline, 1,2,3,4-tetrahydro-2,3-bis(1-methyl-2-propenyl)-(113477-58-0)

Safety Data

• Hazardous Substances Data: 113477-58-0(Hazardous Substances Data)

Upstream product

• 91-19-0 2,3-diethynylquinoxaline 
• 36306-56-6 crotylmagnesium bromide 

Relevant articles and documents

REACTION OF QUINOXALINES WITH β,γ-UNSATURATED GRIGNARD REAGENTS. SYNTHESIS OF ALLYL-, ALLENYL-, PROPARGYL-QUINOXALINE DERIVATIVES.

Mono- and bis-addition reactions of the β,γ-unsaturated Grignard reagents 2 and 6 to the C=N bonds of quinoxalines 1 afford high yields of dihydroquinoxalines 4 and tetrahydroquinoxalines 3.Dehydrogenation of 4g-l and 3a-c with DDQ leads to allylic quinoxalines 1i-m and 1e-g respectively in very good yields.Allylic and propargylic quinoxalines 1m and 1s can conveniently be synthesized by "cross-coupling" of 2-chloro-3-methylquinoxaline with 2c and 6a.