1135265-47-2Relevant academic research and scientific papers
An efficient method for the preparation of tertiary esters by palladium-catalyzed alkoxycarbonylation of aryl bromides
Xin, Zhuo,Gogsig, Thomas M.,Lindhardt, Anders T.,Skrydstrup, Troels
supporting information; experimental part, p. 284 - 287 (2012/02/16)
The palladium-catalyzed alkoxycarbonylation of aryl bromides is described for the efficient preparation of tertiary esters. The protocol proved compatible with a wide variety of functionalized (hetero)aromatic bromides, as well as several different sterically hindered tertiary alcohols, affording the alkoxycarbonylated products in high yields. Finally, the formation of aromatic trityl esters is discussed.
