113543-33-2

Basic information

• Product Name: (S)-4-Benzyl-3-((S)-2-bromo-4-methyl-pentanoyl)-oxazolidin-2-one
• CAS NO: 113543-33-2
• Molecular Weight: 354.244
• Mol File: 113543-33-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-4-Benzyl-3-((S)-2-bromo-4-methyl-pentanoyl)-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-Benzyl-3-((S)-2-bromo-4-methyl-pentanoyl)-oxazolidin-2-one(113543-33-2)
• EPA Substance Registry System: (S)-4-Benzyl-3-((S)-2-bromo-4-methyl-pentanoyl)-oxazolidin-2-one(113543-33-2)

Safety Data

• Hazardous Substances Data: 113543-33-2(Hazardous Substances Data)

Upstream product

• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 646-07-1 4-Methylpentanoic acid 

Downstream Products

• 113543-42-3 (3(2R),4S)-3-(2-azido-4-methyl-1-oxopentyl)-4-(phenylmethyl)-2-oxazolidinone 
• 328-38-1 (R)-leucine 

Relevant articles and documents

ASYMMETRIC HALOGENATION OF CHIRAL IMIDE ENOLATES. A GENERAL APPROACH TO THE SYNTHESIS OF ENANTIOMERICALLY PURE α-AMINO ACIDS.

The chiral N-acyl oxazolidones 2, as the derived dibutyl boron enolates, have been demonstrated to undergo diastereoselective bromination and subsequent azide displacement to give the α-azido carboximides 4a (5 cases).These adducts may be hydrolyzed under mild conditions to the enantiomerically pure α-azido carboxylic acids 5a.