1135446-29-5Relevant academic research and scientific papers
DIRECT ANTI-MARKOVNIKOV ADDITION OF ACIDS TO ALKENES
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Paragraph 0109, (2016/05/02)
A method of making an anti-Markovnikov addition product, comprises reacting an acid with an alkene or alkyne in a dual catalyst reaction system to the exclusion of oxygen to produce said anti-Markovnikov addition product; the dual catalyst reaction system comprising a single electron oxidation catalyst in combination with a hydrogen atom donor catalyst. Dual catalyst composition useful for carrying out such methods are also described.
Anti-markovnikov hydroamination of alkenes catalyzed by an organic photoredox system
Nguyen, Tien M.,Nicewicz, David A.
supporting information, p. 9588 - 9591 (2013/07/26)
Herein we report a metal-free method for the direct anti-Markovnikov hydroamination of unsaturated amines. Irradiation of the amine substrates with visible light in the presence of catalytic quantities of easily synthesized 9-mesityl-10-methylacridinium t
