113546-07-9Relevant academic research and scientific papers
Nucleophilic Reactions of Acetals, Alkyl Sulfonates, and Oxiranes with Diisobutylaluminum Benzenetellurolate
Sasaki, Kazuaki,Mori, Toshiharu,Doi, Yoshitaka,Kawachi, Akinori,Aso, Yoshio,et al.
, p. 415 - 418 (2007/10/02)
Diisobutylaluminum benzenetellurolate was proved to be an effective nucleophilic reagent toward acetals, alkyl sulfonates, and oxiranes to give the corresponding tellurides.These reactions showed the characteristics of an SN2 type.When the substitution reactions were sterically hindered, olefins and allylic alcohols were obtained from alkyl sulfonates and oxiranes, respectively.
