113598-54-2Relevant academic research and scientific papers
Reaction of 3-Amino-2-alkenimines with Alkali Metals: Unexpected Synthesis of Substituted 4-(Arylamino)quinolines
Barluenga, Jose,Aguilar, Enrique,Joglar, Jesus,Olano, Bernardo,Fustero, Santos
, p. 2596 - 2598 (2007/10/02)
A study of the reduction of 3-amino-2-alkenimines 1 with alkali metals is reported.The nature of the alkali metal plays an important role in the course of the process.In this context, a new and simple method for the regioselective synthesis of 4-(arylamino)quinolines 4 from 1 and sodium or potassium is described.
Mild and Regiospecific Reduction of Masked 1,3-Dicarbonyl Derivatives to Monocarbonyl Compounds and Primary and Secodary Amines
Barluenga, Jose,Aguilar, Enrique,Olano, Bernardo,Fustero, Santos
, p. 1741 - 1744 (2007/10/02)
The regiospecific reduction of masked 1,3-dicarbonyl compounds to the corresponding saturated monocarbonyl 3 or iminic 4 compounds via 3-amino-2-alkenimines 1 is described.The formation of 3 and 4 can be explained in terms of a double reduction process from 1.A simple method for the synthesis of primary and secondary amines 6 is also described.
