113619-47-9Relevant academic research and scientific papers
Isolation and characterization of hydroformylation 'intermediates' from stoichiometric reactions between phosphinoalkenes and some heterobinuclear complexes
Coutinho, Kevin J.,Dickson, Ron S.,Fallon, Gary D.,Jackson, W. Roy,De Simone, Tania,Skelton, Brian W.,White, Allan H.
, p. 3193 - 3199 (2007/10/03)
Some heterobimetallic acyl and μ-acyl-rhodium complexes have been isolated from reactions of the phosphidobridged complexes (OC)4M(μ-PPh2)2RhH(CO)(PPh3) with the phosphinoalkenes Ph2P(CH2)
The Stereochemistry of Organometallic Compounds. XXXVII. Regio- and Stereo-control in the Rhodium-Catalysed Hydroformylation of Some Alkenylphosphines
Jackson, W. Roy,Perlmutter, Patrick,Suh, Guem-Hee,Tasdelen, E. Elizabeth
, p. 951 - 966 (2007/10/02)
Good to excellent regiocontrol can be obtained for the internal product of rhodium-catalysed hydroformylation of a range of alkenylphosphines.Excellent stereo- as well as regio-control can also be obtained for reactions of some cyclic alkenylphosphines.
Chelation Control in the Hydroformylation of Terminal Alkenes
Jackson, W. Roy,Perlmutter, Patrick,Suh, Guem-Hee
, p. 724 - 725 (2007/10/02)
Hydroformylation of phosphine-bearing terminal alkenes can lead to a complete reversal of regioselection to that observed for simpler alkenes.
