1136232-83-1Relevant academic research and scientific papers
Gold- and silver-catalyzed allylic alkylation of 1,3-dicarbonyl compounds with allylic alcohols
Kothandaraman, Prasath,Rao, Weidong,Zhang, Xiaoxiang,Chan, Philip Wai Hong
experimental part, p. 1833 - 1838 (2009/06/20)
A highly efficient gold- and silver-catalyzed allylic alkylation of 1,3-dicarbonyl compounds with allylic alcohols has been developed. The reaction was shown to proceed expediently for a wide variety of 1,3-dicarbonyl compounds and allylic alcohols, including 1° and terminal ones, under very mild conditions at room temperature in good to excellent yields (55-96%).
