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113625-71-1

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113625-71-1 Usage

General Description

(1R, 2R)-2-Methoxycyclohexanol, also known as cis-2-methoxycyclohexanol, is a compound belonging to the family of cyclohexanols. It is a colorless liquid with a faint floral odor, and it is commonly used in the manufacturing of fragrances and flavors. This chemical is produced via the reduction of the corresponding ketone, and it is also used as a solvent in various chemical processes. Additionally, (1R, 2R)-2-Methoxycyclohexanol has been investigated for its potential therapeutic properties, including its anti-inflammatory and analgesic effects. Overall, this compound has a variety of industrial and pharmaceutical applications due to its unique chemical and physical properties.

Check Digit Verification of cas no

The CAS Registry Mumber 113625-71-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,3,6,2 and 5 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 113625-71:
(8*1)+(7*1)+(6*3)+(5*6)+(4*2)+(3*5)+(2*7)+(1*1)=101
101 % 10 = 1
So 113625-71-1 is a valid CAS Registry Number.

113625-71-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (1R, 2R)-2-METHOXYCYCLOHEXANOL

1.2 Other means of identification

Product number -
Other names R-MOL

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:113625-71-1 SDS

113625-71-1Relevant articles and documents

Rapid ring-opening reactions of epoxides using microwave irradiation

Torborg, Christian,Hughes, David D.,Buckle, Richard,Robinson, Mathew W. C.,Bagley, Mark C.,Graham, Andrew E.

, p. 205 - 211 (2008)

Copper tetrafluoroborate catalyzes the ring-opening of epoxides with primary, secondary, and tertiary alcohols in short reaction times under microwave irradiation to give β-alkoxyalcohol products in excellent yields. Copyright Taylor & Francis Group, LLC.

Magnesium hydrogensulfate: A cheap and efficient catalyst for the conversion of epoxides into β-alkoxy alcohols, vicinal-diols, and thiiranes

Salehi, Peyman,Khodaei, Mohammad Mahdi,Zolfigol, Mohammad Ali,Keyvan, Afsaneh

, p. 3041 - 3048 (2003)

The nucleophilic ring opening reactions of epoxides by aliphatic alcohols and water are achieved efficiently in the presence of catalytic amounts of magnesium hydrogensulfate, Mg(HSO4)2, with high degree of regioselectivity. The reactions are chemoselective and many of the other functional groups such as ethereal carbon oxygen bonds as well as carbon-carbon double bond remain intact under the reaction conditions. Epoxides also react with thiourea or ammonium thiocyanate in the presence of Mg(HSO 4)2 to afford the corresponding thiiranes in good to excellent yields.

Novel polymer-supported ruthenium and iron complexes that catalyze the conversion of epoxides into diols or diol mono-ethers: Clean and recyclable catalysts

Lee, Sun Hwa,Lee, Eun Yong,Yoo, Dong-Woo,Hong, Sung Jin,Lee, Jung Hwan,Kwak, Han,Lee, Young Min,Kim, Jinheung,Kim, Cheal,Lee, Jin-Kyu

, p. 1579 - 1582 (2007)

Polymer-supported metal (Fe or Ru) complexes for epoxide ring opening reactions were successfully prepared by anchoring the bis(2-picolyl)amine ligand onto the polymer poly(chloromethylstyrene-co-divinylbenzene) (PCD); the catalysts showed heterogeneous catalytic activity and easy recyclability in the ring opening reactions of various epoxide substrates with methanol or H 2O at room temperature under mild and neutral conditions. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

Epoxide ring-opening and Meinwald rearrangement reactions of epoxides catalyzed by mesoporous aluminosilicates

Robinson, Mathew W. C.,Davies, A. Matthew,Buckle, Richard,Mabbett, Ian,Taylor, Stuart H.,Graham, Andrew E.

, p. 2559 - 2564 (2009)

Mesoporous aluminosilicates efficiently catalyze the ring-opening of epoxides to produce β-alkoxyalcohols in high yields under extremely mild reaction conditions. These materials also catalyze the corresponding Meinwald rearrangement in non-nucleophilic solvents to give aldehydes which can be trapped in situ to provide the corresponding acetals in an efficient tandem process. The Royal Society of Chemistry 2009.

Structure and heterogeneous catalytic activity of a coordination polymer containing Cu(NO3)2 and Cu(H2O) 22+ units bridged alternatively by btp ligands (btp=2,6-bis(N′-1,2,4-triazolyl)pyridine)

Sung, Jin Hong,Jin, Soo Seo,Ji, Young Ryu,Jung, Hwan Lee,Kim, Cheal,Kim, Sung-Jin,Kim, Youngmee,Lough, Alan J.

, p. 22 - 28 (2005)

The reaction of Cu(NO3)2 containing NH 4PF6 with btp ligands produced a new polymeric compound 1 containing Cu(H2O)22+ and Cu(NO3)2 units alternatively bridged by btp ligands with H-bonds between copper-bonded water and nitrate oxygen atoms. Crystal Data: M=1465.97, space group P2/n, a=11.6300(3) ?, b=12.8000(4) ?, c=19.2960(6) ?, β=98.6200(19)°, V=2840.03(15) ?3, Z=2, μ=0.926 mm-1, Dc=1.714 Mg/m3, R=0.0629, wR=0.1614. The polymeric compound 1 has shown the heterogeneous catalytic activity for the ring opening of epoxides under mild conditions. This catalyst system appears to be an efficient, mild, and easily recyclable method for the alcoholysis of epoxides. In addition, the heterogeneous catalyst 1 has, surprisingly, shown even better catalytic activity than copper salt system in homogeneous condition.

Fiber-supported Fe(iii) complex catalyst in spinning basket reactor for cleaner ring-opening of epoxides with alcohols

Shi, Xian-Lei,Sun, Benyu,Hu, Qianqian,Chen, Yongju,Duan, Peigao

, p. 3573 - 3582 (2019)

Herein, a newly designed fiber-supported iron catalyst was successfully synthesized by rooting diamine ligands into the surface layer of commercially available polyacrylonitrile fiber and then utilizing the diamine groups to immobilize Fe(iii) ions for heterogeneous catalytic ring-opening reactions. The resulting materials were characterized and observed in detail by elemental analysis, mechanical properties, FTIR spectroscopy and morphology during both the preparation and the utilization processes. Moreover, the fiber catalyst was used in the spinning basket reactor-mediated ring-opening of various epoxides by a series of alcohols under mild reaction conditions, giving good to quantitative yields of the corresponding β-alkoxy alcohols. In addition, the fiber catalyst in the impellers of the agitation system was shown to be reusable multiple times without leaching of the Fe(iii) ions, and when stored on the shelf remained equally active for at least three months. Furthermore, the catalytic system was convenient and effective for scaling-up experiments and thereby has prospects in industrial applications.

Heterogeneous Catalysis of Nucleophilic Substitution

Hodson, Lisa F.,Parker, Tom M.,Whittaker, David

, p. 1427 - 1428 (1993)

The opening of an epoxide ring by attack of a nucleophile can be catalysed by the heterogeneous catalyst, crystalline polymeric zirconium phosphate.

Fe3+-montmorillonite: An efficient heterogeneous catalyst for highly regioselective alcoholysis of epoxides

Choudary, Boyapati M.,Sudha, Yepuri

, p. 2989 - 2992 (1996)

Fe3+- exchanged montmorillonite (Fe3+ -mont) has shown to be a very efficient catalyst for regio and stereoselective alcoholysis of epoxides in primary, secondary and tertiary alcohols as solvents and nucleophiles. Copyright

Electrogenerated Acid as an Efficient Catalyst for Alcoholyses and Hydrolyses of Epoxides

Safavi, Afsaneh,Iranpoor, Nasser,Fotuhi, Lida

, p. 2591 - 2594 (1995)

The electrochemical transformation of different epoxides to their corresponding β-alkoxy alcohols and diols was achieved by using an electrogenerated acid-catalyst.A competitive ring-opening reaction of activated epoxides in the presence of deactivated epoxides was also successfully carried out in both alcohols and water.

MBA-cross-linked poly(N-vinyl-2-pyrrolidone)/ferric chloride macromolecular coordination complex as a novel and recyclable Lewis acid catalyst: Synthesis, characterization, and performance toward for regioselective ring-opening alcoholysis of epoxides

Rahmatpour, Ali,Zamani, Maryam

, (2021/09/30)

A novel macromolecular-metal coordination complex, MBA-cross-linked PNVP/FeCl3 material was fabricated by immobilization of water intolerant ferric chloride onto the porous cross-linked poly(N-vinyl-2-pyrrolidone) carrier beads as a macromolecular ligand or carrier which was prepared by suspension free-radical copolymerization of N-vinyl-2-pyrrolidone (NVP) and N,N′-methylene bis-acrylamide (MBA) as a crosslinking agent in water. The obtained PNVP/FeCl3 was characterized by UV/vis and FT-IR spectroscopies, TGA, FE-SEM, EDX, and ICP techniques. This heterogenized version of ferric chloride is a convenient and safe alternative to highly water intolerant ferric chloride. The catalytic performance of (PNVP/FeCl3) as an efficient and recyclable polymeric Lewis acid catalyst was appropriately probed in the regio-and stereoselective nucleophilic ring opening of various epoxides with various alcohols in excellent yields with TOF up to 182.48 h?1 without generating any waste. The activity data indicate that this heterogeneous catalyst is very active and could be easily recovered, and reused at least six times without appreciable loss of activity indicating its stability under experimental conditions.

Synthesis and structure of an air-stable bis(pentamethylcyclopentadienyl) zirconium pentafluorbezenesulfonate and its application in catalytic epoxide ring-opening reactions

Li, Ningbo,Wang, Lingxiao,Wang, Haojiang,Qiao, Jie,Zhao, Wenjie,Xu, Xinhua,Liang, Zhiwu

, p. 1033 - 1039 (2018/02/06)

An air-stable mononuclear complex of bis(pentamethylcyclopentadienyl) zirconium pentafluorbezenesulfonate was successfully synthesized by treating C6F5SO3Ag with [(CH3)5Cp]2ZrCl2, which showed the cationic uninuclear structure of [{(CH3)5Cp}2Zr(CH3CN)2(H2O)][OSO2C6F5]2·CH3CN (1) confirmed by the X-ray analysis. Complex 1 was also characterized by other techniques and found to have the good nature of air-stability, water tolerance, thermally-stability and strong Lewis-acidity. Moreover, the complex showed high catalytic activity and recyclability in catalytic epoxide ring-opening reactions by amines or alcohols. This catalytic system affords a simple and efficient approach for synthesis of β-amino alcohols or β-alkoxy alcohols.

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