113656-58-9

Upstream product

• 113643-42-8 (R)-3-<(2R,5S)-5-<(2R,5R,6S)-5-benzyloxy-5-ethyl-6-methyltetrahydropyran-yl>-2-methoxy-5-methyltetrahydrofuran-2-yl>-3-(4-methoxybenzyloxy)prop-1-yne 
• 110653-60-6 (2R,4S,5S,6S,7R)-6-ethyl-5,7-isopropylidenedioxy-2,4-dimethylnonanal 
• 110653-68-4 Toluene-4-sulfonic acid (2S,5S,6S)-5-benzyloxy-5-ethyl-2,6-dihydroxy-heptyl ester 
• 824-94-2 p-methoxybenzyl chloride 
• 120269-74-1 (2R,3R,6S)-6-((2R,5R,6S)-5-Benzyloxy-5-ethyl-6-methyl-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxy)-heptane-1,3,6-triol 
• 329899-60-7 (3aR,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 113643-38-2 (2R,3R)-2,4-isopropylidenedioxy-3-(4-methoxybenzyloxy)butanal 
• 126394-13-6 methyl <(2R,5R,6S)-5-benzyloxy-5-ethyl-6-methyltetrahydropyran>-2-carboxylate 
• 126394-12-5 (2S,5S,6S)-5-Benzyloxy-5-ethyl-heptane-1,2,6-triol 
• 107207-31-8 (2R,3R)-2,4-isopropylidenedioxy-3-(4-methoxybenzyloxy)butanol 
• 113643-40-6 <(2R,5R,6S)-5-benzyloxy-5-ethyl-6-methyltetrahydropyran>-2-methanol 
• 126365-85-3 (2R,4S)-4-((4S,5S,6R)-5,6-Diethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-2-methyl-pentan-1-ol 
• 126365-83-1 (3R,5S,6S)-6-((1S,2R)-1-Ethyl-2-hydroxy-butyl)-3,5-dimethyl-tetrahydro-pyran-2-ol 
• 126365-84-2 (2R,4S,5S,6S,7R)-6-Ethyl-2,4-dimethyl-nonane-1,5,7-triol 

Downstream Products

• 113643-43-9 (3R,4S)-4-{(2S,3S,5R)-6-[(R)-3-[(S)-5-((2R,5R,6S)-5-Benzyloxy-5-ethyl-6-methyl-tetrahydro-pyran-2-yl)-2-methoxy-5-methyl-tetrahydro-furan-2-yl]-3-(4-methoxy-benzyloxy)-prop-1-ynyl]-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl}-hexan-3-ol 
• 108194-54-3 (R)-4-[(2S,9S,10S,12R,15R)-2-((2R,5R,6S)-5-Ethyl-5-hydroxy-6-methyl-tetrahydro-pyran-2-yl)-15-hydroxy-2,10,12-trimethyl-1,6,8-trioxa-dispiro[4.1.5.3]pentadec-13-en-9-yl]-hexan-3-one 
• 113643-44-0 (R)-1-<(3R,5R,6S)-6-<(1R,2R)-2-acetoxy-1-ethylbutyl>-2-methoxy-3,5-dimethyltetrahydropyran-2-yl>-3-<(5S)-5-<(2R,5R,6S)-5-benzyloxy-5-ethyl-6-methyltetrahydropyran-2-yl>-2-methoxy-5-methyltetrahydrofuran-2-yl>-3-(4-methoxybenzyloxy)prop-1-yne 
• 113643-45-1 (1Z,3R)-1-<(3R,5R,6S)-6-<(1R,2R)-2-acetoxy-1-ethylbutyl>-2-methoxy-3,5-dimethyltetrahydropyran-2-yl>-3-<(5S)-5-<(2R,5R,6S)-5-benzyloxy-5-ethyl-6-methyltetrahydropyran-2-yl>-2-methoxy-5-methyltetrahydrofuran-2-yl>-3-(4-methoxybenzyloxy)prop-1-ene 
• 126419-22-5 (3R,4S)-4-[(2S,9S,10S,12R,15R)-2-((2R,5R,6S)-5-Benzyloxy-5-ethyl-6-methyl-tetrahydro-pyran-2-yl)-15-(4-methoxy-benzyloxy)-2,10,12-trimethyl-1,6,8-trioxa-dispiro[4.1.5.3]pentadec-13-en-9-yl]-hexan-3-ol 
• 126365-87-5 Acetic acid (1R,2S)-2-[(2S,9S,10S,12R,15R)-2-((2R,5R,6S)-5-benzyloxy-5-ethyl-6-methyl-tetrahydro-pyran-2-yl)-15-(4-methoxy-benzyloxy)-2,10,12-trimethyl-1,6,8-trioxa-dispiro[4.1.5.3]pentadec-13-en-9-yl]-1-ethyl-butyl ester 
• 113643-46-2 (2S,9S,10S,12R,13Z,15R)-2-<(2R,5R,6S)-benzyloxy-5-ethyl-6-methyltetrahydropyran-2-yl>-9-<(R)-1-ethyl-2-oxobutyl>-15-(4-methoxybenzyloxy)-2,10,12-trimethyl-1,6,8-trioxadispiro<4.1.5.3>pentadec-13-ene 
• 53003-10-4 salinomycin 

Relevant academic research and scientific papers

STEREOSELECTIVE SYNTHESIS OF THE MIDDLE (C10-C17) AND RIGHT (C18-C30) SEGMENTS, AND THEIR COUPLING TO COMPLETE A FORMAL SYNTHESIS OF THE POLYETHER ANTIBIOTIC SALINOMYCIN

The middle (C10-C17) and right (C18-C30) segments of the polyether antibiotic salinomycin were stereoselectively synthesized from D-glucose, D-mannitol, and ethyl L-lactate.Coupling of the two segments followed by construction of the bisketal ring system gave the C10-C30 segment, which was already converted to salinomycin by Kishy.