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113666-64-1

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113666-64-1 Usage

Chemical Properties

Colorless liquid. Insoluble in water; soluble in alcohol and ether. Combustible.

Uses

Antifoaming agent, intermediate, perfume fixatives, plasticizer.

Check Digit Verification of cas no

The CAS Registry Mumber 113666-64-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,3,6,6 and 6 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 113666-64:
(8*1)+(7*1)+(6*3)+(5*6)+(4*6)+(3*6)+(2*6)+(1*4)=121
121 % 10 = 1
So 113666-64-1 is a valid CAS Registry Number.
InChI:InChI=1/C11H24O/c1-3-4-5-6-7-8-9-10-11(2)12/h11-12H,3-10H2,1-2H3/t11-/m0/s1

113666-64-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-UNDECANOL

1.2 Other means of identification

Product number -
Other names 2-Undecanol, (±)-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:113666-64-1 SDS

113666-64-1Relevant articles and documents

High-efficiency and minimum-waste continuous kinetic resolution of racemic alcohols by using lipase in supercritical carbon dioxide

Matsuda, Tomoko,Watanabe, Kazunori,Harada, Tadao,Nakamura, Kaoru,Arita, Yoshitaka,Misumi, Yukibiro,Ichikawa, Shinichiro,Ikariya, Takao

, p. 2286 - 2287 (2004)

A novel continuous-flow scCO2 process for kinetic resolution of racemic alcohols can be performed with an immobilized lipase to lead to a quantitative mixture of the corresponding optically active acetates with up to 99% ee and unreacted alcohols with up to 99% ee, in which the productivity of the optically active compounds was improved by over 400 times compared to the corresponding batch reaction using scCO2.

Stereoselective opening of acetals derived from dimethyl tartrate

Guindon,Simoneaua,Yoakima,Gorysa,Lemieuxa,Ogilvie

, p. 5453 - 5456 (1991)

Acetals of dimethyl tartrate can be used to prepare optically active secondary alcohols from the corresponding aldehydes. The key step involves treatment of the acetals with dialkylboron bromides and higher order cuprates. The process involves an unusual

Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode

Buhaibeh, Ruqaya,Filippov, Oleg A.,Bruneau-Voisine, Antoine,Willot, Jérémy,Duhayon, Carine,Valyaev, Dmitry A.,Lugan, No?l,Canac, Yves,Sortais, Jean-Baptiste

supporting information, p. 6727 - 6731 (2019/04/17)

Deprotonation of the MnI NHC-phosphine complex fac-[MnBr(CO)3(κ2P,C-Ph2PCH2NHC)] (2) under a H2 atmosphere readily gives the hydride fac-[MnH(CO)3(κ2P,C-Ph2PCH2NHC)] (3) via the intermediacy of the highly reactive 18-e NHC-phosphinomethanide complex fac-[Mn(CO)3(κ3P,C,C-Ph2PCHNHC)] (6 a). DFT calculations revealed that the preferred reaction mechanism involves the unsaturated 16-e mangana-substituted phosphonium ylide complex fac-[Mn(CO)3(κ2P,C-Ph2P=CHNHC)] (6 b) as key intermediate able to activate H2 via a non-classical mode of metal-ligand cooperation implying a formal λ5-P–λ3-P phosphorus valence change. Complex 2 is shown to be one of the most efficient pre-catalysts for ketone hydrogenation in the MnI series reported to date (TON up to 6200).

Rhenium and manganese complexes bearing amino-bis(phosphinite) ligands: Synthesis, characterization, and catalytic activity in hydrogenation of ketones

Li, Haoran,Wei, Duo,Bruneau-Voisine, Antoine,Ducamp, Maxime,Henrion, Micka?l,Roisnel, Thierry,Dorcet, Vincent,Darcel, Christophe,Carpentier, Jean-Fran?ois,Soulé, Jean-Fran?ois,Sortais, Jean-Baptiste

supporting information, p. 1271 - 1279 (2018/04/30)

A series of rhenium and manganese complexes supported by easily accessible and easily tunable amino-bisphosphinite ligands was prepared and characterized by NMR and IR spectroscopy, HR mass spectrometry, elemental analysis, and X-ray diffraction studies. These complexes have been tested in the hydrogenation of ketones. Notably, one of the rhenium complexes, bearing an NH moiety, proved significantly more active than the rest of the series. The reaction proceeds well at 120 °C, under 50 bar of H2, in the presence of 0.5 mol % of catalyst and 1 mol % of tBuOK. Interestingly, activation of the precatalyst could be followed stepwise by NMR and a rhenium hydride was characterized by X-ray diffraction studies.

Hydrogenation of Carbonyl Derivatives with a Well-Defined Rhenium Precatalyst

Wei, Duo,Roisnel, Thierry,Darcel, Christophe,Clot, Eric,Sortais, Jean-Baptiste

, p. 80 - 83 (2017/01/17)

The first efficient and general rhenium-catalyzed hydrogenation of carbonyl derivatives was developed. The key to the success of the reaction was the use of a well-defined rhenium complex bearing a tridentate diphosphinoamino ligand as the catalyst (0.5 mol %) at 70 °C in the presence of H2 (30 bar). The mechanism of the reaction was investigated by DFT(PBE0-D3) calculations.

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