113748-68-8

Basic information

• Product Name: ((bromo(2,2,6,6-tetramethylpiperidino)boryl)(2,6-diisopropylphenyl)amino)antimony dibromide
• CAS NO: 113748-68-8
• Molecular Weight: 687.795
• Mol File: 113748-68-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((bromo(2,2,6,6-tetramethylpiperidino)boryl)(2,6-diisopropylphenyl)amino)antimony dibromide(CAS DataBase Reference)
• NIST Chemistry Reference: ((bromo(2,2,6,6-tetramethylpiperidino)boryl)(2,6-diisopropylphenyl)amino)antimony dibromide(113748-68-8)
• EPA Substance Registry System: ((bromo(2,2,6,6-tetramethylpiperidino)boryl)(2,6-diisopropylphenyl)amino)antimony dibromide(113748-68-8)

Safety Data

• Hazardous Substances Data: 113748-68-8(Hazardous Substances Data)

Upstream product

• 113748-54-2 (2,6-diisopropylphenylimino)(2,2,6,6-tetramethylpiperidino)borane 
• 7789-61-9 antimony(III) bromide 

Relevant articles and documents

Contributions to the Chemistry of Boron, 191. - Addition and Insertion Reactions of Amino-imino-boranes with the Trihalides of Main-Group V Elements

The tetramethylpiperidino-imino-boranes 1a, b react with the trihalides of phosphorus, arsenic, and antimony (Hal = F, Cl, Br, with PF3 as an exception) to yield novel N-boryl-substituted amino elements dihalides 2 and 3.However, 1:1 adducts having a structure analogous to allene result with the iodides as well as with BiCl3.NMR spectra reveal no intramolecular interaction of the tetramethylpiperidino group with the element E atom in the insertion products in contrast to the X-ray result on 3b and 3e.Both molecules adapt a Ψ-trigonal bipyramidal coordination at E in the solid state.