113767-85-4Relevant academic research and scientific papers
Copper-catalyzed enantioselective 1,4-addition to α,β- unsaturated aldehydes
Palais, Laetitia,Babel, Lucille,Quintard, Adrien,Belot, Sebastien,Alexakis, Alexandre
supporting information; experimental part, p. 1988 - 1991 (2010/07/10)
Figure presented The first asymmetric Cu-catalyzed conjugate addition of dialkylzinc zinc reagents to a large scope of enals in presence of phosphoramidite, SimplePhos, or (R)-BINAP ligands with enantiomeric excesses up to 90% is reported. Moreover, ACA of Grignard reagents afforded moderate to good 1,4-regioselectivities with enantioselectivities up to 90%.
Regio- and Stereoselective Synthesis of Allylic and Homoallylic Alcohols by the Reductive Desulfonylation of Allylic Sulfone Derivatives. Application to the Syntheses of (+/-)-Lavandulol and Isolavandulol
Inomata, Katsuhiko,Igarashi, Susumu,Mohri, Mitsunobu,Yamamoto, Taku,Kinoshita, Hideki,Kotake, Hiroshi
, p. 707 - 710 (2007/10/02)
Regio- and stereoselective desulfonylation of β-tosylhomoallylic alcohols provided a convenient method for the preparation of allylic and homoallylic alcohols. (+/-)-Lavandulol and isolavandulol were synthesized in excellent yields by this method.
