113784-08-0

Basic information

• Product Name: 2,3-di-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl fluoride
• Synonyms: 2,3-di-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl fluoride
• CAS NO: 113784-08-0
• Molecular Weight: 402.463
• Mol File: 113784-08-0.mol

Chemical Properties

• CAS DataBase Reference: 2,3-di-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl fluoride(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-di-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl fluoride(113784-08-0)
• EPA Substance Registry System: 2,3-di-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl fluoride(113784-08-0)

Safety Data

• Hazardous Substances Data: 113784-08-0(Hazardous Substances Data)

Upstream product

• 117780-23-1 2,3-di-O-benzyl-4,6-O-isopropylidene-D-galactopyranose 

Downstream Products

• 128745-63-1 allyl O-(6-O-acetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-(1->4)-O-(6-O-acetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-β-D-galactopyranoside 
• 113765-19-8 O-(2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-α-D-galactopyranosyl fluoride 
• 113765-37-0 O-(2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-β-D-galactopyranosyl fluoride 
• 128745-62-0 C₇₀H₈₀O₁₈ 
• 113765-33-6 allyl O-(2,3-di-O-benzyl-α-D-galactopyranosyl)-(1->4)-O-(6-O-acetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-β-D-galactopyranoside 
• 113765-23-4 allyl O-(6-O-acetyl-2,3-di-O-benzyl-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-β-D-galactopyranoside 
• 128745-59-5 O-(2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-D-galactopyranose 
• 115173-49-4 C₉₂H₁₀₄O₂₄ 
• 113765-29-0 allyl O-(2,3-di-O-benzyl-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-β-D-galactopyranoside 
• 113765-28-9 allyl O-(2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-β-D-galactopyranoside 
• 113765-30-3 tert-butyldiphenylsilyl O-(2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-galactopyranosyl)-(1->4)-6-O-acetyl-2,3-di-O-benzyl-β-D-galactopyranoside 

Relevant articles and documents

A HIGHLY STEREOCONTROLLED SYNTHESIS OF THE PROPYL GLYCOSIDE OF A DECAGALACTURONIC ACID, A MODEL COMPOUND FOR THE ENDOGENOUS PHYTOALEXIN ELICITOR-ACTIVE OLIGOGALACTURONIC ACIDS

Propyl O-(α-D-galactopyranosyluronic acid)-4)-O-(α-D-galactopyranosyluronic acid)>8-(1->4)-β-D-galactopyranosiduronic acid, a model compound for a phytoalexin-elicitor-active oligogalacturonic acid, was synthesized in a highly stereocontrolled manner

A HIGHLY EFFICIENT, PRACTICAL, AND STEREOSELECTIVE APPROACH TO THE SYNTHESIS OF α 1 --> 4 LINKED GALACTOOLIGOSACCHARIDES

Exclusive formation of α14 linked galactopyranosyl oligosaccharides could be achieved by employing glycosyl fluorides.The observed diastereofacial selectivity was explained in terms of the nucleophilic attack of glycosyl acceptors toward convex face of the glycosyl fluorides.