1138026-24-0

Basic information

• Product Name: N,N-bis(2,4-dimethoxybenzyl)-1-S-(2,3,4,6-tetra-O-acetyl)-D-glucopyranosylsulfonamide
• Synonyms: N,N-bis(2,4-dimethoxybenzyl)-1-S-(2,3,4,6-tetra-O-acetyl)-D-glucopyranosylsulfonamide
• CAS NO: 1138026-24-0
• Molecular Weight: 711.741
• Mol File: 1138026-24-0.mol

Chemical Properties

• CAS DataBase Reference: N,N-bis(2,4-dimethoxybenzyl)-1-S-(2,3,4,6-tetra-O-acetyl)-D-glucopyranosylsulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis(2,4-dimethoxybenzyl)-1-S-(2,3,4,6-tetra-O-acetyl)-D-glucopyranosylsulfonamide(1138026-24-0)
• EPA Substance Registry System: N,N-bis(2,4-dimethoxybenzyl)-1-S-(2,3,4,6-tetra-O-acetyl)-D-glucopyranosylsulfonamide(1138026-24-0)

Safety Data

• Hazardous Substances Data: 1138026-24-0(Hazardous Substances Data)

Upstream product

• 1138026-22-8 N,N-bis(2,4-dimethoxybenzyl)-1-S-(2,3,4,6-tetra-O-acetyl)-D-glucopyranosylsulfenamide 

Relevant articles and documents

Synthesis of S-glycosyl primary sulfonamides

The synthesis of S-glycosyl sulfonamides wherein the primary sulfonamide functional group (-SO2NH2) is directly attached to the anomeric position of a carbohydrate moiety is reported. Our general approach consists of first introducing a thioacetate group at the anomeric center of a per-O-acetylated sugar derivative From this follows formation of a glycosyl sulfenamide (sugar-SNR2), oxidation of the sulfenamide to give a glycosyl N-protected sulfonamide (sugar-SO2NR2), and removal of the sulfonamide protecting (R) group to yield a primary sulfonamide at the anomeric center (sugar-SO2NH2). A variety of monoand disaccharide derivatives were synthesized using this new methodology