113879-91-7

Upstream product

• 86447-91-8 Benzyl-4-O-benzoyl-2-brom-2,6-didesoxy-β-D-glucopyranosid 
• 1133160-47-0 benzyl 4-O-benzoyl-2,6-dideoxy-2-(p-tolylthio)-β-D-glucopyranoside 
• 86447-90-7 Benzoic acid (2R,3R,4S,5R,6R)-6-benzyloxy-5-bromo-4-formyloxy-2-methyl-tetrahydro-pyran-3-yl ester 

Downstream Products

• 1133162-86-3 benzyl 4-O-benzoyl-2,6-dideoxy-2-(p-tolylthio)-β-D-glucopyranosyl-(1->3)-4-O-benzoyl-2,6-dideoxy-β-D-arabino-hexopyranoside 
• 108319-60-4 benzyl 4-O-benzoyl-3-C-methylen-2,3,6-trideoxy-β-D-erythro-hexopyranoside 
• 108319-62-6 benzyl 3,3'-anhydro-4-O-benzoyl-2,6-dideoxy-3-C-hydroxymethyl-β-D-ribo-hexopyranoside 
• 108319-63-7 benzyl 3,3'-anhydro-2,6-dideoxy-3-C-hydroxymethyl-β-D-ribo-hexopyranoside 
• 108319-61-5 benzyl 3-C-methylen-2,3,6-trideoxy-β-D-erythro-hexopyranoside 
• 113879-96-2 Benzyl-2,6-didesoxy-3-C-methyl-β-D-arabino-hexopyranosid 
• 108319-64-8 Benzyl-2,6-didesoxy-3-C-methyl-β-D-ribo-hexopyranosid 
• 108319-59-1 Benzyl-4-O-benzoyl-2,6-didesoxy-β-D-erythro-hexopyranosid-3-ulose 

Relevant academic research and scientific papers

2,3-Anhydrosugars in glycoside bond synthesis. Application to 2,6-dideoxypyranosides

We describe here the first use of 2,3-anhydrosugars as glycosylating agents for the preparation of 2-deoxypyranosides. In particular, the methodology was used to assemble 2,6-dideoxysugar glycosides. Glycosylation of a panel of alcohols with one of two 6-

NEUE SYNTHESEN VON AUREOLSAEURETRISACCHARIDEN

The silver trifluoromethylsulfonate-promoted condensation of 4-O-benzoyl-2-bromo-2,6-dideoxy-3-O-formyl-α-D-glucopyranosyl bromide (4) and benzyl 4-O-benzoyl-2-bromo-2,6-dideoxy-β-D-glucopyranoside (5) yielded a disaccharide, which, after ester cleavage,