113892-66-3

Upstream product

• 113892-76-5 (2S,4S,5R,6S)-5-Benzoyloxy-4-(tert-butyl-dimethyl-silanyloxy)-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzoyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 113892-63-0 (2S,4S,5S,6R)-5-Benzoyloxy-4-hydroxy-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzoyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 113892-64-1 (2S,4S,5S,6R)-4-Benzoyloxy-5-hydroxy-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzoyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 

Downstream Products

• 113892-68-5 (2S,4S,5R,6R)-2-((2R,3S,4R,5R,6R)-6-Acetoxy-3,4,5-tris-benzoyloxy-tetrahydro-pyran-2-ylmethoxy)-5-acetylamino-4-benzoyloxy-6-((1S,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 113892-67-4 (2S,4S,5R,6R)-5-Acetylamino-4-benzoyloxy-2-((2R,3S,4R,5R,6R)-3,4,5-tris-benzoyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-6-((1S,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective total syntheses of the naturally occurring enantiomers of N-acetylneuraminic acid and 3-deoxy-D-manno-2-octulosonic acid. A new and stereospecific approach to sialo and 3-deoxy-D-manno-2-octulosonic acid conjugates

The total syntheses of the title compounds have been achieved. A critical element of these syntheses was the concept of using a furan ring as a surrogate for a carboxylic acid. The furyl diene 22 reacted with the R and S enantiomers of 2-(phenylseleno)pro