113894-35-2Relevant academic research and scientific papers
Fluorinated butene derivatives and methods for their preparation
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, (2008/06/13)
New chemical reactions of 1,1,2-trifluoro-1,3-butadiene provide simple access to a series of new fluorinated alkene derivatives. These derivatives provide a simple, general methodology for the stereocontrolled preparation of 2-fluoro-2-alkenoate esters an
1,1,2-Trifluoro-1,3-butadiene: A Convenient C4 Intermediate for Functionalized Monofluoroolefins
Matsuo, Noritada,Kende, Andrew S.
, p. 2304 - 2308 (2007/10/02)
The regioselective methoxybromination of 1,1,2-trifluoro-1,3-butadiene to give (Z)-4-bromo-1-methoxy-1,1,2-trifluoro-2-butene (3a) is reported.This can easily be transformed into a wide range of (Z)-2-fluoro-2-alkenoates (4a-c, 5).The reaction of benzenes
