113900-60-0

Basic information

• Product Name: Piperazine, 1,4-bis(1-methylpropyl)-
• CAS NO: 113900-60-0
• Molecular Formula: C12H26N2
• Mol File: 113900-60-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Piperazine, 1,4-bis(1-methylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Piperazine, 1,4-bis(1-methylpropyl)-(113900-60-0)
• EPA Substance Registry System: Piperazine, 1,4-bis(1-methylpropyl)-(113900-60-0)

Safety Data

• Hazardous Substances Data: 113900-60-0(Hazardous Substances Data)

Upstream product

• 110-85-0 piperazine 
• 78-76-2 s-butyl bromide 

Relevant articles and documents

Ruthenium catalyzed reactions of ethylene glycol with primary amines: steric factors and selectivity control

The selectivity of reactions of ethylene glycol with primary amines in the presence of RuCl2(PPh3)3 at 120 deg C is highly dependent on the steric nature of the amine.Selectivity to di-amination is favored by smaller alkyl groups on the amine while large amines cleanly yield ethanolamines.This contrasts with the results obtained with secondary amines at this temperature, in which ruthenium-triphenylphosphine catalyst systems always favor mono-amination.In the case of sec-butyl amine, where almost equal amounts of mono- and di-aminated product are obtained, the selecti vity can be shifted to mono-amination by the addition of excess triphenylphosphine.The steric effects seen in these reactions are consistent with standard steric parameters availble from the literature.