113974-07-5

Upstream product

• 102682-12-2 Benzoic acid (2S,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-2-((Z)-2-methoxycarbonyl-vinyl)-tetrahydro-pyran-3-yl ester 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 102682-12-2 Benzoic acid (2S,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-2-((Z)-2-methoxycarbonyl-vinyl)-tetrahydro-pyran-3-yl ester 
• 102650-44-2 Benzoic acid (2S,3R,4S,6S)-2-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 102650-46-4 Benzoic acid (2R,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-2-formyl-6-furan-2-yl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 102650-45-3 Benzoic acid (2S,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-2-hydroxymethyl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 113974-13-3 Benzoic acid (2S,3S,6R)-6-furan-2-yl-6-methoxy-4-oxo-2-((R)-1-phenylselanyl-ethyl)-tetrahydro-pyran-3-yl ester 
• 113974-15-5 Benzoic acid (2S,3R,4R,6R)-6-furan-2-yl-4-hydroxy-6-methoxy-2-((R)-1-phenylselanyl-ethyl)-tetrahydro-pyran-3-yl ester 
• 113924-25-7 Benzoic acid (2R,3S,4S,6S)-6-furan-2-yl-4-hydroxy-6-methoxy-2-((S)-1-phenylselanyl-ethyl)-tetrahydro-pyran-3-yl ester 
• 113974-05-3 Benzoic acid (2R,3S,4S)-6-furan-2-yl-4-hydroxy-2-((S)-1-phenylselanyl-ethyl)-3,4-dihydro-2H-pyran-3-yl ester 
• 113974-03-1 Benzoic acid (2R,3R)-6-furan-2-yl-4-oxo-2-((S)-1-phenylselanyl-ethyl)-3,4-dihydro-2H-pyran-3-yl ester 
• 113892-51-6 Benzoic acid (1Z,3Z)-4-furan-2-yl-4-methoxy-2-trimethylsilanyloxy-buta-1,3-dienyl ester 
• 92622-30-5 Benzoic acid (Z)-4-furan-2-yl-4-methoxy-2-oxo-but-3-enyl ester 
• 113892-52-7 Benzoic acid (2R,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-2-((S)-1-phenylselanyl-ethyl)-tetrahydro-pyran-3-yl ester 

Downstream Products

• 113924-26-8 C₇₁H₉₂O₁₃Si 
• 113892-74-3 C₅₆H₆₆O₁₈Si 
• 113974-11-1 (2S,4S,5R,6R)-5-Azido-4-benzoyloxy-2-methoxy-6-((1S,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 113974-08-6 (2S,4S,5R,6S)-5-Benzoyloxy-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 113974-12-2 (2S,4S,5R,6R)-5-Acetylamino-4-benzoyloxy-2-methoxy-6-((1S,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 113974-10-0 (2S,4S,5S,6R)-4-Benzoyloxy-5-hydroxy-2-methoxy-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 113974-09-7 (2S,4S,5S,6R)-5-Benzoyloxy-4-hydroxy-2-methoxy-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 6730-43-4 N-Acetyl-β-D-neuraminylsaeure-methyl-methylglycosid 
• 114027-54-2 C₄₇H₅₀O₁₂Si 
• 102650-49-7 C₄₇H₅₀O₁₂Si 
• 102650-50-0 (2R,4R,5S,6R)-5-Benzoyloxy-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-6-((1S,2S)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 102650-52-2 (2S,4S,5S,6R)-4-Benzoyloxy-5-hydroxy-2-methoxy-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 102650-51-1 (2S,4S,5S,6R)-5-Benzoyloxy-4-hydroxy-2-methoxy-6-((1R,2R)-1,2,3-tris-benzoyloxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 102650-48-6 Benzoic acid (2R,3S,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-furan-2-yl-6-methoxy-2-((1S,2S)-1,2,3-trihydroxy-propyl)-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Stereoselective total syntheses of the naturally occurring enantiomers of N-acetylneuraminic acid and 3-deoxy-D-manno-2-octulosonic acid. A new and stereospecific approach to sialo and 3-deoxy-D-manno-2-octulosonic acid conjugates

The total syntheses of the title compounds have been achieved. A critical element of these syntheses was the concept of using a furan ring as a surrogate for a carboxylic acid. The furyl diene 22 reacted with the R and S enantiomers of 2-(phenylseleno)pro

The Total Synthesis of (+/-)-N-Acetylneuraminic Acid (NANA): A Remarkable Hydroxylation of a (Z)-Enoate

A total synthesis of the title compound was achieved.A key feature of the synthesis involved a stereospecific hydroxylation of a (Z)-carbomethoxyvinyl pyranoside.