113978-91-9

Basic information

• Product Name: TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE
• Synonyms: TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE;TRI-N-BUTYLPHOSPHINE TETRAFLUOROBORATE,&;Tri-n-butylphosphoniumtetrafluoroborate,99%;tributylphosphine tetrafluoroborate;Tributylphosphine tetrafluoroborate,97%;Tributylphosphonium tetrafluoroborate;Tributylphosphine tetrafluoroborate 97%;[n-Bu3PH]BF4
• CAS NO: 113978-91-9
• Molecular Formula: BF₄*C₁₂H₂₇P*H
• Molecular Weight: 290.13
• Product Categories: Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds;organophosphine salt;Achiral Phosphine;Alkyl Phosphine;P-BF4
• Mol File: 113978-91-9.mol
• Article Data: 2

Chemical Properties

• Melting Point: 50-53 °C(lit.)
• Flash Point: >221 °F
• Appearance: white/Powder
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE(113978-91-9)
• EPA Substance Registry System: TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE(113978-91-9)

Safety Data

• Statements: 36/37/38
• Safety Statements: 22-24/25
• WGK Germany: 3
• Hazardous Substances Data: 113978-91-9(Hazardous Substances Data)

Usage

Reaction

Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes. Catalyst in Baylis-Hillman reactions. Azide reductions. Acylation of alcohols by anhydrides. Ligand for formate reduction of allyl carbonates. Synthesis of aromatic nitriles via Pd C-H functionalization.

General Description

May contain approximately 5% of other butyl isomers.

Upstream product

• 998-40-3 tributylphosphine 

Downstream Products

• 998-40-3 tributylphosphine 

Relevant articles and documents

An acidity scale of tetrafluoroborate salts of phosphonium and iron hydride compounds in [D2]dichIoromethane

Equilibrium constants (K) for reactions between acids and the conjugate base forms of a number of phosphonium salts, [HPR3][BF4], and iron hydrides, [Fe(CO)3H(PR3)2][BF 4], in CD2Cl2 have been determined by means of 31P and 1H NMR spectroscopy at 20°C. The anchor compound chosen for pKCD2Cl2 determinations was [HPCy 3][BF4] with a pKCD2Cl2 value of 9.7, as assigned by literature convention (Cy: cyclohexyl). A continuous scale of pKCD2Cl2 values covering the range from 9.7 to -3 was created and correlated with the ΔH values reported by Angelici and co-workers and literature pKa values. The pKCD2Cl2 values for 15 other hydride or dihydrogen complexes of the iron group elements and of diethyl ether were also placed on this scale. The crystal structures of [Fe(CO) 3H(PCy2Ph)2][BF4] and [Fe(CO) 3(PCy2Ph)2] revealed that the frans-oriented, bulky, unsymmetrical phosphane ligands distort the equatorial plane of the complexes. The acidity of iron carbonyl hydrides is an important feature of the reactions of iron hydrogenase enzymes.