113985-83-4Relevant academic research and scientific papers
Complexes of Acyclic and Cyclic Diazathiaalkanes. Crystal Structures of 1,7-Diaza-4-thiaheptane-tricarbonyl-molybdenum(0), 1-Thia-4,7-diazacyclononane-tricarbonyl-molybdenum(0) and 1-Thia-4,7-diazacyclononane-tricarbonyl-rhenium(I) Bromide
Hoffmann, Peter,Steinhoff, Andreas,Mattes, Reiner
, p. 867 - 873 (2007/10/02)
The reactions of Mo(CO)6, W(CO)6 and Re(CO)6Br with the ligand 1-thia-4,7-diazacyclononane (C6H14N2S = L) yield crystals of LMo(CO)3 (4a), LW(CO)3 (4b) and LRe(CO)3Br (5).An improved synthesis of L has been developed, and the structures of 4a and 5 have b
