1140233-99-3Relevant academic research and scientific papers
Metal-Free Approach for the Synthesis of N-Aryl Sulfoximines via Aryne Intermediate
Aithagani, Sravan Kumar,Dara, Saidulu,Munagala, Gurunadham,Aruri, Hariprasad,Yadav, Mahipal,Sharma, Shweta,Vishwakarma, Ram A.,Singh, Parvinder Pal
, p. 5547 - 5549 (2015/12/01)
A metal-free and operationally simple N-arylation of NH-sulfoximines with aryne precursors is reported. Transition metal-free reaction conditions and shorter reaction times are the highlights of the present method. The mild optimized condition was also found to be suitable with enantiopure substrates.
Mild copper-TBAF-catalyzed N-arylation of sulfoximines with aryl siloxanes
Kim, Jaeeun,Ok, Jinpyo,Kim, Sanghyuck,Choi, Wonseok,Lee, Phil Ho
supporting information, p. 4602 - 4605 (2015/01/09)
An efficient copper-TBAF-catalyzed C-N bond formation of sulfoximines with arylsiloxanes in dichloromethane at room temperature, affording the desired N-aryl sulfoximines in good to excellent yields under an oxygen atmosphere, is reported. This method complements the existing synthetic approaches due to some advantageous properties of arylsiloxanes such as availability, low toxicity, ease of handling, high stability, and environmental benignity under mild reaction conditions, thus opening a new approach to practical C-N bond formation.
Iron-catalyzed C-N cross-coupling of sulfoximines with aryl iodides
Correa, Arkaitz,Bolm, Carsten
supporting information; experimental part, p. 391 - 394 (2009/04/10)
An inexpensive and experimentally simple, iron-catalyzed N-arylation reaction of NH-sulfoximines with aryl iodides is reported. This complementary method to the known palladium- and copper-catalyzed ones features the use of a combination of environmentall
