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114032-61-0

{C5(CH3)5Ir(CH3)C8H6S}(1+)*(BF4)(1-)={C5(CH3)5Ir(CH3)C8H6S}BF4 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 114032-61-0 Structure

  • Basic information

    1. Product Name: {C5(CH3)5Ir(CH3)C8H6S}(1+)*(BF4)(1-)={C5(CH3)5Ir(CH3)C8H6S}BF4
    2. Synonyms: {C5(CH3)5Ir(CH3)C8H6S}(1+)*(BF4)(1-)={C5(CH3)5Ir(CH3)C8H6S}BF4
    3. CAS NO:114032-61-0
    4. Molecular Formula:
    5. Molecular Weight: 563.49
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 114032-61-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: {C5(CH3)5Ir(CH3)C8H6S}(1+)*(BF4)(1-)={C5(CH3)5Ir(CH3)C8H6S}BF4(CAS DataBase Reference)
    10. NIST Chemistry Reference: {C5(CH3)5Ir(CH3)C8H6S}(1+)*(BF4)(1-)={C5(CH3)5Ir(CH3)C8H6S}BF4(114032-61-0)
    11. EPA Substance Registry System: {C5(CH3)5Ir(CH3)C8H6S}(1+)*(BF4)(1-)={C5(CH3)5Ir(CH3)C8H6S}BF4(114032-61-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 114032-61-0(Hazardous Substances Data)

114032-61-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 114032-61-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,0,3 and 2 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 114032-61:
(8*1)+(7*1)+(6*4)+(5*0)+(4*3)+(3*2)+(2*6)+(1*1)=70
70 % 10 = 0
So 114032-61-0 is a valid CAS Registry Number.

114032-61-0Downstream Products

114032-61-0Relevant articles and documents

Hydrodesulfurization model complexes: Nucleophilic addition to π-coordinated benzo[b]thiophenes and thiophene

Huckett, Sara C.,Angelici, Robert J.

, p. 1491 - 1500 (2008/10/08)

The π-bound thiophene (T) and benzo[b]thiophene (BT) complexes [CpRu(BT)]+, [Cp*Ir(BT)]2+, and [Cp*Ir(T)]2+, models for the adsorption of thiophenic compounds to hydrodesulfurization (HDS) catalyst surfaces, react with a variety of nucleophiles (H-, MeO-, (MeO2C)2CH-, EtS-, and phosphines). The BT complexes yield the first isolable transition-metal cyclohexadienyl complexes derived from fused ring aromatic ligands; four isomers of each cyclohexadienyl complex are produced. The isomers result from addition at the four carbons on the benzene ring; for the nucleophiles studied, addition occurs preferentially at the carbon closest to the sulfur atom, C7. This isomer of CpRu(BT·H) has been characterized by an X-ray structure determination. The T complex reacts with phosphines to produce [Cp*Ir(η4-T·PR3)]2+. Double nucleophilic addition reactions (H- and MeO-) of [Cp*Ir(BT)]2+ and [Cp*Ir(3-MeBT)]2+ are also discussed. Reaction of either NaBEt3H or Cp2Co with [Cp*Ir(T)]2+ results in a 2e reduction of the Ir complex. On the basis of 1H NMR data and by analogy to related complexes, this product is formulated as Cp*Ir(η4-T).

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