114050-40-7

Basic information

• Product Name: 5-(Pyridin-2-ylsulfanyl)-pentanoic acid methyl ester
• Synonyms: 5-(Pyridin-2-ylsulfanyl)-pentanoic acid methyl ester
• CAS NO: 114050-40-7
• Molecular Weight: 225.312
• Mol File: 114050-40-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(Pyridin-2-ylsulfanyl)-pentanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(Pyridin-2-ylsulfanyl)-pentanoic acid methyl ester(114050-40-7)
• EPA Substance Registry System: 5-(Pyridin-2-ylsulfanyl)-pentanoic acid methyl ester(114050-40-7)

Safety Data

• Hazardous Substances Data: 114050-40-7(Hazardous Substances Data)

Upstream product

• 114050-32-7 Hexanedioic acid methyl ester 2-thioxo-2H-pyridin-1-yl ester 

Relevant articles and documents

THE INVENTION OF RADICAL REACTIONS. PART XV. SOME MECHANISTIC ASPECTS OF THE DECARBOXYLATIVE REARRANGEMENT OF THIOHYDROXAMIC ESTERS

Esters (mixed anhydrides) derived from aliphatic or alicyclic carboxylic acids (RCO2H) and thiohydroxamic acids 2 or 3 undergo a thermally or photochemically induced radical chain reaction to give sulphides 4 with loss of carbon dioxide.On irradiation at low temperature however, the chain reaction is essentially suppressed.Under these conditions moderate to good yields of dimers R-R are obtained from primary acids.The mechanistic and synthetic implications of these observations are discussed.