114057-67-9Relevant academic research and scientific papers
Diastereoselective Syntheses of Highly Substituted Methyl Tetrahydrofuran-3-carboxylates by Reactions of γ-Lactols with Silylated Nucleophiles
Brueckner, Christiane,Holzinger, Hiltrud,Reissig, Hans-Ulrich
, p. 2450 - 2456 (2007/10/02)
Hydroxyalkylation of enolates generated from methyl 2-siloxycyclopropanecarboxylates 1 followed by fluoride-induced ring opening gives γ-lactols as key intermediates.Their reduction with triethylsilane / BF3*OEt2 affords methyl tetrahydrofuran-3-carboxyla
