114057-68-0

Basic information

• Product Name: 3-Furancarboxylic acid, 5-(1,1-dimethylethyl)tetrahydro-2,2-diphenyl-5-(1,2-propadienyl)-, methyl ester, cis-
• CAS NO: 114057-68-0
• Molecular Formula: C25H28O3
• Molecular Weight: 376.496
• Mol File: 114057-68-0.mol

Chemical Properties

• CAS DataBase Reference: 3-Furancarboxylic acid, 5-(1,1-dimethylethyl)tetrahydro-2,2-diphenyl-5-(1,2-propadienyl)-, methyl ester, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Furancarboxylic acid, 5-(1,1-dimethylethyl)tetrahydro-2,2-diphenyl-5-(1,2-propadienyl)-, methyl ester, cis-(114057-68-0)
• EPA Substance Registry System: 3-Furancarboxylic acid, 5-(1,1-dimethylethyl)tetrahydro-2,2-diphenyl-5-(1,2-propadienyl)-, methyl ester, cis-(114057-68-0)

Safety Data

• Hazardous Substances Data: 114057-68-0(Hazardous Substances Data)

Upstream product

• 13361-64-3 trimethyl(propargyl)silane 
• 103619-89-2 2-(Hydroxydiphenylmethyl)-5,5-dimethyl-4-oxohexansaeure-methylester 

Relevant articles and documents

Diastereoselective Syntheses of Highly Substituted Methyl Tetrahydrofuran-3-carboxylates by Reactions of γ-Lactols with Silylated Nucleophiles

Hydroxyalkylation of enolates generated from methyl 2-siloxycyclopropanecarboxylates 1 followed by fluoride-induced ring opening gives γ-lactols as key intermediates.Their reduction with triethylsilane / BF3*OEt2 affords methyl tetrahydrofuran-3-carboxyla