114059-53-9

Upstream product

• 119794-57-9 tert-butyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-glycero-hex-3-enopyranosid-2-ulose 
• 119794-72-8 2,2-Dimethyl-propionic acid (2S,3R,4S,6R)-4-amino-6-tert-butoxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-3-ylmethyl ester 
• 114094-16-5 tert-butyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-4-C-<(trimethylacetoxy)methyl>-α-D-erythro-hexopyranosid-2-ulose 
• 114094-38-1 tert-butyl 6-O-(tert-butyldimethylsilyl)-3-(N,N'-dicarbobenzyloxyhydrazino)-2,3,4-trideoxy-4-C-<(trimethylacetoxy)methyl>-2-C-methylene-α-D-arabino-hexopyranoside 
• 114059-50-6 tert-butyl 6-O-(tert-butyldimethylsilyl)-3-(N,N'-dicarbobenzyloxyhydrazino)-3,4-dideoxy-4-C-<(trimethylacetoxy)methyl>-α-D-arabino-hexopyranosid-2-ulose 
• 119794-63-7 C₄₂H₆₈N₂O₁₀Si₂ 
• 114094-36-9 tert-butyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-4-C-(hydroxymethyl)-α-D-erythro-hexopyranosid-2-ulose 
• 114059-52-8 2,2-Dimethyl-propionic acid (2S,3R,4S,5R,6R)-4-benzyloxycarbonylamino-6-tert-butoxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-3-ylmethyl ester 
• 3366-47-0 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabinohex-1-enopyranose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 501-53-1 benzyl chloroformate 
• 119794-74-0 tert-butyl 6-O-(tert-butyldimethylsilyl)-3-(carbobenzyloxyamino)-2,3,4-trideoxy-4-C-(hydroxymethyl)-2-C-methyl-α-D-glucopyranoside 
• 114059-51-7 2,2-Dimethyl-propionic acid (2S,3R,4S,6R)-4-benzyloxycarbonylamino-6-tert-butoxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-3-ylmethyl ester 
• 119794-56-8 tert-butyl 3,4-dideoxy-α-D-glycero-hex-3-enopyranosid-2-ulose 

Downstream Products

• 110919-04-5 (3R,4R,5S,6R)-4-benzyloxycarbonylamino-3,4,5,6-tetrahydro-5-methoxycarbonyl-3,6-dimethyl-2H-pyran-2-one 
• 119794-80-8 tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-6-iodo-2-C-methyl-α-D-glucopyranoside 
• 114059-54-0 tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside 
• 119794-83-1 (2R,3S,4R,5R)-4-Benzyloxycarbonylamino-6-hydroxy-2,5-dimethyl-tetrahydro-pyran-3-carboxylic acid methyl ester 
• 119794-79-5 (2S,3S,4R,5R,6R)-4-Benzyloxycarbonylamino-6-tert-butoxy-2-hydroxymethyl-5-methyl-tetrahydro-pyran-3-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Electrophilic Amination as a Route to Deoxyamino Sugars: Synthesis of the Key Intermediate for 1β-Methylcarbapenem

The application of electrophilic amination of keto sugars as a route to deoxyamino sugars by the reaction of sugar enolates with dibenzyl azodicarboxylate has been explored.Although the success of the reaction is dependent on several factors, such as the location of the carbonyl group and the substitution pattern on the pyranosidulose ring, the process is synthetically promising.This has been demonstrated by preparation of the protected Melillo Lactone analogue 18, a key intermediate for 1β-methylcarbapenem.