114066-01-2Relevant academic research and scientific papers
MICHAEL ADDITION OF NOVEL ACYL ANION EQUIVALENTS GENERATED BY THE ELECTROREDUCTION OF OXAZOLINIUM SALTS TO ACTIVATED OLEFINS
Shono, Tatsuya,Kashimura, Shigenori,Yamaguchi, Yoshihide,Kuwata, Fumitaka
, p. 4411 - 4414 (2007/10/02)
Electroreduction of oxazolinium salts gave novel acyl anion equivalents (AAEs), and the Michael addition of these AAEs to activated olefins has been found to be promoted effectively by the addition of chlorotrimethylsilane into the reaction system.This reaction was applied to the synthesis of cis-jasmone and dihydrojasmone.
