114091-96-2

Upstream product

• 114091-94-0 3-(2-Methoxycarbonyl-ethyl)-5-[4-(2-methoxycarbonyl-ethyl)-3-methoxycarbonylmethyl-2-methyl-5-thioxo-2,5-dihydro-1H-pyrrol-2-ylmethyl]-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 114091-93-9 3-(2-Methoxycarbonyl-ethyl)-5-[4-(2-methoxycarbonyl-ethyl)-3-methoxycarbonylmethyl-2-methyl-5-oxo-2,5-dihydro-1H-pyrrol-2-ylmethyl]-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 114125-36-9 5-[5-Chloro-4-(2-methoxycarbonyl-ethyl)-3-methoxycarbonylmethyl-2-methyl-2H-pyrrol-2-ylmethyl]-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester 
• 114091-92-8 3-(2-Iodo-4-methoxycarbonylmethyl-5-methyl-1H-pyrrol-3-yl)-propionic acid methyl ester 
• 50622-67-8 5-acetoxymethyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-pyrrole-2-carboxylic acid benzyl ester 
• 114091-95-1 2-[5-Benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-methoxycarbonylmethylpyrrol-2-ylmethyl]-4-(2-methoxycarbonylethyl)-3-methoxycarbonylmethyl-2-methyl-2H-pyrrole 
• 52201-14-6 3-(4-methoxycarbonylmethyl-5-methyl-pyrrol-3-yl)-propionic acid methyl ester 
• 50622-60-1 3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-pyrrole-2-carboxylic acid benzyl ester 

Relevant academic research and scientific papers

Biosynthesis of porphyrins and related macrocycles. Part 48. The rearrangement of 2H-pyrroles (pyrrolenines) related to the proposed spiro-intermediate for porphyrin biosynthesis

It is proposed that the biosynthesis of uroporphyrinogen III 3, the parent precursor of the natural porphyrins, chlorins and corrins, involves a 2H-pyrrole (pyrrolenine) 2 as a key intermediate. Model pyrrolenines have now been used to show that (a) pyrro

Selenomethylpyrroles: Their Use for Synthesis of Dipyrrylmethanes (Dipyrrins), Tripyranes and Bilanes

Phenylselenomethylpyrroles react rapidly under mild conditions with α-free pyrroles in the presence of copper(I) triflate to form pyrrole-CH2-pyrrole systems in preparative yields.The same coupling reaction can also be achieved thermally or photochemicall

Selectivity in the Rearrangement of a Di(pyrrolylmethyl)-2H-pyrrole

A di(pyrrolylmethyl)-2H-pyrrole has been synthesised and its ready acid-catalysed rearrangement shows that one of the two possible modes of cleavage is preferred; this mode corresponds to that required for the formation of uroporphyrinogen-III from the putative spiro intermediate.