114113-40-5

Basic information

• Product Name: Thiophene, 1-[[(cyanoimino)(4-methylphenyl)methyl]imino]-1,1,2,3,4,5-hexahydro-, 1-oxide
• CAS NO: 114113-40-5
• Molecular Formula: C13H15N3OS
• Molecular Weight: 261.348
• Mol File: 114113-40-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Thiophene, 1-[[(cyanoimino)(4-methylphenyl)methyl]imino]-1,1,2,3,4,5-hexahydro-, 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Thiophene, 1-[[(cyanoimino)(4-methylphenyl)methyl]imino]-1,1,2,3,4,5-hexahydro-, 1-oxide(114113-40-5)
• EPA Substance Registry System: Thiophene, 1-[[(cyanoimino)(4-methylphenyl)methyl]imino]-1,1,2,3,4,5-hexahydro-, 1-oxide(114113-40-5)

Safety Data

• Hazardous Substances Data: 114113-40-5(Hazardous Substances Data)

Upstream product

• 50578-18-2 S,S-tetramethylenesulfoximide 
• 86700-29-0 methyl N-cyano-4-methylbenzimidate 

Downstream Products

• 114113-56-3 3a-Oxo-5-p-tolyl-3aλ⁶-thia-4,6-diaza-indan-7-ylamine 

Relevant articles and documents

New Thienothiadiazines and Pyridothiadiazines from N-Cyanoimidates and Sulfoximides

Reaction of the N-cyanoimidates 1a-d, 1f-h with the sulfoximides 2a-b yields the open chain products 3a-d, 3f-h, 4a-d and 4f-h. 3e and 4e are obtained from 3f and 4f in boiling pyrrolidine.If treated with sodium hydride 3a-e cyclise to the thienothiadiazines 5a-e. 4a-d react under the same conditions in a different way and give the pyrimidothiadiazines 8a-d. 3f and 4f are converted into the thiazoles 10a-b with thioglycolic acid methyl ester.