114131-01-0Relevant academic research and scientific papers
Application of electrogenerated triphenylmethyl anion as a base for alkylation of arylacetic esters and arylacetonitriles and isomerization of allylbenzenes
Suzuki, Shohei,Kato, Mitsuko,Nakajima, Shoichi
, p. 357 - 361 (2007/10/02)
Phenylacetic esters and phenylacetonitriles were alkylated with alkyl halides, at the position α to an ester or nitrile, either at room temperature (20 deg C) or at -78 deg C, by making use of electrogenerated triphenylmethyl anion (trityl anion).Double-bond isomerization of allylbenzenes was also effectively accomplished by use of this electrogenerated base (EGB).
