114133-30-1Relevant articles and documents
Metal-metal-bond-assisted substitution reaction of a heterobimetallic phosphido-bridged Mo-Fe complex
Hsiao, Shu-Min,Shyu, Shin-Guang
, p. 1151 - 1154 (1998)
The heterobimetallic phosphido-bridged complexes CpMo(CO)2(M-PPh2)Fe(CO)4 (1) and CpMo(CO)3(μ-PPh2)Fe(CO)4 (2) were prepared by the reaction of CpMo(CO)3PPh2 with Fe2(CO)9. The reaction between 1 and Lewis bases L(L = P(OMe)3, PPh2H, PPh3) at ambient temperatures produced CpMo(CO)2(μ-PPh2)Fe(CO)3(L) (3) with L regiospecifically coordinated to Fe. However, 2 did not react with L under similar conditions.