114156-01-3Relevant academic research and scientific papers
Preparation of S,S-Diphenyl-N-(trimethylsilyl)sulfimine and Reactions with Tungsten Hexafluoride - X-Ray Structure Analysis of F4W(N=SPh2)2
Roesky, Herbert W.,Zimmer, Michael,Noltemeyer, Mathias,Sheldrick, George M.
, p. 1377 - 1380 (2007/10/02)
Ph2S=NH reacts with Me3SiNMe2 to give S,S-diphenyl-N-(trimethylsilyl)sulfimine (1) in a metathesis.Reaction of WF6 with 1 in a 1:1 molar ratio leads to F5WN=SPh2 (2); a 1:2 molar ratio results in the formation of F4W(N=SPh2)2 (3).The structure of 3 is confirmed by an X-ray analsis.
