1141929-40-9Relevant academic research and scientific papers
The regio- and stereo-selective formation of allylic chlorides during the overman rearrangement of trichloroacetimidates derived from certain brominated conduritols
Matveenko, Maria,Willis, Anthony C.,Banwell, Martin G.
experimental part, p. 64 - 68 (2009/07/18)
Microwave irradiation of imidate 2 at 165C affords a ～3:1 mixture of the Overman rearrangement product 3 and the allylic chloride 4 (83% combined yield). Under the same conditions the deoxy-conduritol 6 gives a comparable mixture of compounds 7 and 8. The
