1141932-38-8Relevant articles and documents
Synthesis of bicyclo[3.1.0]hexan-2-ones by manganese(III) oxidation in ethanol
Asahi, Kentaro,Nishino, Hiroshi
, p. 409 - 423 (2009)
N-Propenyl-3-oxobutanamides underwent the manga- nese(III)-induced oxidative intramolecular cyclization in ethanol to produce 3-azabicyclo[3.1.0] hexan-2-ones in good yields. A similar reaction of propenyl 3-oxobutanoates and S-propenyl 3-oxobutanethioates also gave the corresponding 3-oxa- and 3-thiabicyclo[3.1.0]hexan-2-ones. The reaction details, the structure determination, and the reaction pathway are described. Georg Thieme Verlag Stuttgart.