114197-34-1

Basic information

• Product Name: 3-Mercapto-2-methyl-2-(6-methyl-2-phenyl-pyrimidin-4-yl)-propionic acid methyl ester
• CAS NO: 114197-34-1
• Molecular Weight: 302.397
• Mol File: 114197-34-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Mercapto-2-methyl-2-(6-methyl-2-phenyl-pyrimidin-4-yl)-propionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Mercapto-2-methyl-2-(6-methyl-2-phenyl-pyrimidin-4-yl)-propionic acid methyl ester(114197-34-1)
• EPA Substance Registry System: 3-Mercapto-2-methyl-2-(6-methyl-2-phenyl-pyrimidin-4-yl)-propionic acid methyl ester(114197-34-1)

Safety Data

• Hazardous Substances Data: 114197-34-1(Hazardous Substances Data)

Upstream product

• 105759-16-8 6-methyl-2phenylpyrimidine-4(3H)-thione 
• 80-62-6 methacrylic acid methyl ester 

Relevant articles and documents

Photochemical Reactions of Pyrimidinethiones with Alkenes

Photochemical addition reactions of pyrimidinethiones and related compounds with alkenes have been examinated.Irradiation of pyrimidine-4(3H)-thiones (1a) in the presence of electron-poor alkenes gave the 4-mercaptoalkylated pyrimidines (5), whereas irradiation of (1a) in the presence of electron-rich alkenes gave 4-alkylthiopyrimidines (6).Irradiation of quinazoline-4(3H)-thiones (1c-e) and electron-poor alkenes gave 4-subtituted quinazolines (9) and (10).This ready mode of carbon-carbon bond formation provides an efficient and novel method for alkylation of pyrimidine rings.