114221-70-4Relevant academic research and scientific papers
Free-Radical Additions of Diselenides to Dimethyl Acetylenedicarboxylate, Methyl Propiolate, and Dimethyl Maleate
Back, Thomas G.,Krishna, M. Vijaya
, p. 2533 - 2536 (2007/10/02)
The photolysis of diphenyl or dimesityl diselenide with dimethyl acetylenedicarboxylate or methyl propiolate resulted principally in the formation of the corresponding vicinal bisselenides 1a,b,2a,b, and 6a,b via a free-radical chain addition mechanism.Dimethyl maleate underwent a selenyl radical mediated isomerization to dimethyl fumarate when similarly photolyzed with diphenyl diselenide.
