114245-65-7Relevant academic research and scientific papers
Efficient Wittig-Horner Synthesis of Acyclic α-Enones with an Asymmetric Carbon at the γ-Position Using Barium Hydroxide
Ibarra, Carlos Alvarez,Arias, Selma,Fernandez, Maria J.,Sinisterra, Jose V.
, p. 503 - 508 (2007/10/02)
β-Monosubstituted acyclic α-enones with an asymmetric carbon at the γ-position: (E)-(5RS)-5-phenylhex-3-en-2-one, (4a), (E)-(6RS)-2,2-dimethyl-6-phenylhept-4-en-3-one, (4b), (E)-(4RS)-1,4-diphenylpent-2-en-1-one, (4c), (E)-(5RS)-6,6-dimethyl-5-phenylhept-
Ba(OH)2 AS CATALYST IN ORGANIC REACTIONS - PART XIX - STRUCTURE-CATALYTIC ACTIVITY RELATIONSHIP IN THE AdN OF SEVERAL YLIDS TO CH=O GROUP, CATALYZED BY ACTIVATED BARIUM HYDROXIDE CATALYST
Sinisterra, J. V.,Marinas, J. M.,Riquelme, F.,Arias, M. S.
, p. 1431 - 1440 (2007/10/02)
The reactivity of several products R1R2CH-X(1+), 1, (X=N,P,S), which can produce ylids by reaction with bases, has been tested using the activated barium hydroxide catalysts, C-200.Wittig-Horner, Wittig, Corey-Chaykovsky and Kroehnke type reactions have been analyzed.The pKa of 1, and the structure of active sites control the process.When 1 has a strong acid character, the process takes place - dissolving the solid - in homogeneous phase.When 1, has pKa values 11.7), that control the reaction mechanism and the reactivity of adsorbed ylids.
