114262-85-0Relevant academic research and scientific papers
A recyclable fluorous hydrazine-1,2-bis(carbothioate) with NCS as efficient catalysts for acetalization of aldehydes
Zhu, Yi-Wei,Yi, Wen-Bin,Cai, Chun
supporting information, p. 890 - 892 (2013/07/05)
A fluorous hydrazine-carbothioate organocatalyst was prepared. Together with NCS, the catalyst showed a good activity in acetalization of aldehydes and alcohols. It could be recovered from the reaction mixture by fluorous solid-phase extraction (F-SPE) with excellent purity for direct reuse.
NCS with thiourea as highly efficient catalysts for acetalization of aldehydes
Mei,Bentley,Du
supporting information; experimental part, p. 4199 - 4200 (2009/10/04)
NCS/thiourea-mediated acetalization of aldehydes and alcohols has rapidly provided acetals in almost quantitative yields.
Iron(III) chloride-catalyzed convenient one-pot synthesis of homoallyl benzyl ethers starting from aldehydes
Watahiki, Tsutomu,Akabane, Yusuke,Mori, Seiji,Oriyama, Takeshi
, p. 3045 - 3048 (2007/10/03)
(Matrix presented) Iron(III) chloride-catalyzed effective allylation reactions of acetals with allyltrimethylsilane proceeded smoothly in high to excellent yields. In addition, this method could be applied to the one-pot synthesis of homoallyl benzyl ethe
Carbon-carbon bond formation by reactions of allylic alcohol with enoxysilane in the presence of Ir-complex
Matsuda, Isamu,Wakamatsu, Shogo,Komori, Ken-Ichi,Makino, Tatsuya,Itoh, Kenji
, p. 1043 - 1046 (2007/10/03)
Substitution of allylic alcohols to form a carbon-carbon bond is accomplished by a simple reaction of the allylic alcohol itself with an enoxysilane, catalyzed by [Ir(cod)(PPh3)2]X which is activated by H2 molecule. The anion part X of the complexes plays an important role to enhance the rate and product yields of the reactions. The efficacy of the catalyst increases with switching X in the order of PF6-4--.
