114272-52-5Relevant academic research and scientific papers
Reactive Selenoaldehydes Formed from Selenenyl Derivatives by 1,2-Elimination and Trapped in situ as Cycloadducts with Conjugated Dienes
Kirby, Gordon W.,Trethewey, Andrew N.
, p. 1913 - 1922 (2007/10/02)
Selenenyl derivatives, ZCH2SeX, where Z is an electron-withdrawing group (Z=EtO2C, MeO2C, PhCO, PhNHCO, or NC) and X is a leaving group (X=CN, SO3K, Cl, SO2Tol, and N-phthalimido), react with triethylamine to form selenoaldehydes, ZCHSe, by 1,2-eliminatio
GENERATION AND DIENOPHILIC REACTIVITY OF α-OXOSELENOALDEHYDES AND KETONES
Nakayama, Juzo,Akimoto, Keiichi,Niijima, Jun,Hoshino, Masamatsu
, p. 4423 - 4426 (2007/10/02)
The reaction elemental selenium with sulfur ylides stabilized by electron-withdrawing substituent(s) affords a facile method for generation of functionalized selenocarbonyl compounds, which can be effectively trapped by Diels-Alder reaction with 1,3-dienes.
