114272-80-9

Upstream product

• 963-15-5 (Z)-1,2-bis(phenylsulfonyl)ethene 
• 114272-72-9 4,5,6,7-tetrahydro-2-<<4-(trifluoromethyl)phenyl>methylene>-4,7-methano-2H-indene 
• 114272-72-9 (4R,7S)-2-[1-(4-Trifluoromethyl-phenyl)-meth-(Z)-ylidene]-4,5,6,7-tetrahydro-2H-4,7-methano-indene 
• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 6675-72-5 3-isocyclopentadiene 

Relevant academic research and scientific papers

Remote electronic perturbation of π-facial stereoselectivity in [4+2] cycloadditions to isodicyclopentafulvenes. The consequences of p-phenyl substitution

Isodicyclopentafulvenes that carry an exocyclic para-substituted phenyl group as in 11 enter into Diels-Alder cycloaddition with highly reactive dienophiles exclusively from below the plane. The situation with the more sterically hindered and less reactiv

Modulation of ?-Facial Selectivity in Diels-Alder Cycloaddition to Isodicyclopentafulvenes by Remote Para Substitution of an Exocyclic Phenyl Group

Isodicyclopentafulvenes that carry an exocyclic para-substituted phenyl group as in 3 enter into Diels-Alder cycloaddition with highly reactive dienophiles exclusively from below-plane.The situation with the more sterically hindered and less reactive reagent (Z)-1,2-bis(phenylsulfonyl)ethylene is one where addition occurs from both faces.