114272-86-5Relevant academic research and scientific papers
Remote electronic perturbation of π-facial stereoselectivity in [4+2] cycloadditions to isodicyclopentafulvenes. The consequences of p-phenyl substitution
Gugelchuk, Melinda,Paquette, Leo A.
, p. 246 - 253 (2007/10/02)
Isodicyclopentafulvenes that carry an exocyclic para-substituted phenyl group as in 11 enter into Diels-Alder cycloaddition with highly reactive dienophiles exclusively from below the plane. The situation with the more sterically hindered and less reactiv
