114324-58-2Relevant academic research and scientific papers
Activation of Dithiocarbamate by 2-Halothiazolium Salts
Sugimoto, Hirohiko,Makino, Itsuo,Hirai, Kentaro
, p. 2263 - 2267 (2007/10/02)
Activation of dithiocarbamate salts with 2-halo-3-alkyl-4-phenylthiazolium salt and subsequent one-pot nucleophilic reaction with N, S, and O nucleophiles provided substituted thioureas, dithiocarbamates, and thiocarbamates or amides, respectively, under very mild conditions.A useful thiocarbonyl-transfer reaction is also described that consists of activation of imidazolodithiocarbamate and a subsequent one-pot nucleophilic reaction. (Thiocarbonyl)diimidazole is generated in situ.
